City were left on the brink of elimination after both were dismissed in the second half as the Premier League champions again crumbled on the European stage, losing 2-1 on a miserable night at the Etihad Stadium.
City were stunned in the second minute as Seydou Doumbia, who inspired CSKA's comeback from 2-0 down to draw against City a fortnight ago, headed the opener.
Toure curled in a superb free kick to equalise soon after but Doumbia capitalised on poor defending to restore the Russians' lead before the break. It was his fifth goal in four matches against City over the past year.
Fernandinho received a second booking for blocking Ahmed Musa and Toure gave the referee little option as he raised his hands to push away Roman Eremenko.
Both players later apologised.
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